|
|
chlorogenic_acid + CoA <=> caffeoyl-CoA + quinate
|
2.3.1
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
| |
BRENDA:
BS321558
KEGG:
R01945
MetaCyc:
RXN-2622
|
|
|
|
p-coumaric_acid + CoA + ATP <=> 4-coumaroyl-CoA + AMP + diphosphate
|
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.30
phenylacetate---CoA ligase
|
–
–
–
|
| |
BRENDA:
BR63
KEGG:
R01616
MetaCyc:
4-COUMARATE--COA-LIGASE-RXN
SABIO-RK:
1761
|
|
|
|
trans-5-O-caffeoylshikimate + CoA <=> caffeoyl-CoA + shikimate
|
2.3.1
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
| |
BRENDA:
BS320440
KEGG:
R07433
MetaCyc:
RXN-2621
|
|
|
|
S-adenosyl-L-methionine + 5-hydroxyconiferaldehyde <=> H+ + S-adenosyl-L-homocysteine + sinapaldehyde
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
2.1.1.68
caffeate O-methyltransferase
|
–
–
|
| |
BRENDA:
BS319578
KEGG:
R06576
MetaCyc:
RXN-1143
|
|
|
|
4-coumaroyl-CoA + quinate <=> 5-O-p-coumaroylquinic_acid + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
|
| |
BRENDA:
BS320439
KEGG:
R07432
MetaCyc:
RXN-2601
|
|
|
|
4-coumaroyl-CoA + NADPH + H+ <=> 4-coumaraldehyde + CoA + NADP+
|
1.2.1.44
cinnamoyl-CoA reductase
|
–
|
| |
BRENDA:
BS189225;
BS388396
KEGG:
R01615
MetaCyc:
RXN-1101
SABIO-RK:
1760
|
|
|
|
coniferyl_alcohol + NADP+ <=> coniferyl_aldehyde + NADPH + H+
|
1.1.1.194
coniferyl-alcohol dehydrogenase
1.1.1.195
cinnamyl-alcohol dehydrogenase
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.90
aryl-alcohol dehydrogenase
1.1.1.91
aryl-alcohol dehydrogenase (NADP+)
|
–
–
–
–
–
|
| |
BRENDA:
BR36707
KEGG:
R02593
MetaCyc:
RXN-2602
SABIO-RK:
2499
|
|
|
|
H+ + feruloyl-CoA + NADPH <=> coniferyl_aldehyde + NADP+ + CoA
|
1.2.1.44
cinnamoyl-CoA reductase
1.2.1.68
coniferyl-aldehyde dehydrogenase
|
–
–
|
| |
BRENDA:
BS189226
KEGG:
R02193
MetaCyc:
RXN-1106
SABIO-RK:
2166
|
|
|
|
4-coumaroyl-CoA + shikimate <=> 4-coumaroylshikimate + CoA
|
2.3.1.133
shikimate O-hydroxycinnamoyltransferase
2.3.1.140
rosmarinate synthase
2.3.1.99
quinate O-hydroxycinnamoyltransferase
|
–
–
–
|
| |
BRENDA:
BR43994
KEGG:
R02416
MetaCyc:
2.3.1.133-RXN
|
|
|
|
coniferyl_aldehyde + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 5-hydroxyconiferaldehyde + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14
|
–
|
| |
MetaCyc:
RXN-1142
|
|
|
|
5-O-p-coumaroylquinic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> chlorogenic_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
| |
MetaCyc:
1.14.13.36-RXN
|
|
|
|
S-adenosyl-L-methionine + caffeoyl-CoA <=> H+ + feruloyl-CoA + S-adenosyl-L-homocysteine
|
2.1.1.104
caffeoyl-CoA O-methyltransferase
|
–
|
| |
BRENDA:
BR43863
KEGG:
R01942
MetaCyc:
CAFFEOYL-COA-O-METHYLTRANSFERASE-RXN
|
|
|
|
p-coumaryl_alcohol + NADP+ <=> 4-coumaraldehyde + NADPH + H+
|
1.1.1.195
cinnamyl-alcohol dehydrogenase
|
–
|
| |
BRENDA:
BS230433;
BS426143
KEGG:
R07437
MetaCyc:
RXN-1102
SABIO-RK:
3739
|
|
|
|
4-coumaroylshikimate + reduced_[NADPH-hemoprotein_reductase] + O2 <=> trans-5-O-caffeoylshikimate + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.96
5-O-(4-coumaroyl)-D-quinate 3'-monooxygenase
|
–
|
| |
MetaCyc:
RXN-2581
|
|
|
|
sinapyl_alcohol + NADP+ <=> sinapaldehyde + NADPH + H+
|
1.1.1.195
cinnamyl-alcohol dehydrogenase
1.1.1.2
alcohol dehydrogenase (NADP+)
|
–
–
|
| |
BRENDA:
BS187664
KEGG:
R03918
MetaCyc:
RXN-1125
SABIO-RK:
3663
|
|
